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An Encyclopedia on Refrigerant Gas Knowledge

  • Q Introduction of Refrigerant Gas R32

    A
    Basic Introduction

    Difluoromethane is an organic substance with a molecular formula of CH2F2 and a molecular weight of 52.02. It is a colorless gas and is partially miscible with water.
    Used as a dry engraving agent, a substitute for low-temperature refrigerant R-502, or as a mixed refrigerant with HFC-134a and HFC-152a to replace HCFC-22

    Chinese name Difluoromethane
    CAS NO. 75-10-5
    Chinese alias HFC-32
    English name difluoromethane
    English alias R-32
    Molecular formula CH2F2
    Molecular weight 52.02

    CAS Number: 75-10-5
    MDL number: MFCD00039283
    EINECS number: 200-839-4
    RTECS number: PA8537500

    Physical Properties of R32 Gas

    Physical property:
    molecular formula CH2F2
    molecular weight 52.02       
    melting point,℃  -136
    density(25℃) liquid, g/cm³   0.96
    critical temperature,℃          78.52
    critical density ,g/cm³ 0.43
    water solubility℃,W% 0.44
    ODP 0
    GWP 675

    Quality Index of R32 Gas

    Quality index
    purity,%  above 99.93%
    moisture,% ≤0.001 
    acidity,%  ≤0.0001
    evaporated residue,% ≤ 0.01
    chloride (cl-)experiment test permition
    noncondensable gas(v/v),% 1.5
    appearance colorless transparent liquefied gas

    Application of R32 Gas
     
    Difluoromethane is a coolant with zero ozone depletion potential. Difluoromethane and pentafluoroethane can form a constant boiling mixture (called R-410A), which can be used as a substitute for chlorofluorocarbons (also known as Freon) in new coolant systems, mainly to replace HCFC-22 , As a compound medium and low temperature mixed refrigerant. Although it has zero ozone depletion potential, it has a high global warming potential, and its potential is 550 times that of carbon dioxide on a 100-year basis.

  • Q R32 Refrigerant Temperature and Relative Pressure

    A   
    R32 Refrigerant Temperature and Relative Pressure
    Temp. Pressure
    kpa
    Temp. Pressure
    kpa
    Temp. Pressure
    kpa
    kg/cm² kg/cm² kg/cm²
    -51.909 1 18.138 14 43.55 27
    -43.635 1.5 19.395 14.5 44.32 27.5
    -37.323 2 20.619 15 45.079 28
    -32.15 2.5 21.813 15.5 45.828 28.5
    -27.731 3 22.978 16 46.567 29
    -23.85 3.5 24.116 16.5 47.296 29.5
    -20.378 4 25.229 17 48.015 30
    -17.225 4.5 26.317 17.5 48.726 30.5
    -14.331 5 27.382 18 49.428 31
    -11.65 5.5 28.425 18.5 50.121 31.5
    -9.1503 6 29.447 19 50.806 32
    -6.8046 6,5 30.448 19.5 51.482 32.5
    -4.6925 7 31.431 20 52.15 33
    -2.4975 7.5 32.395 20.5 52.811 33.5
    -0.50613 8 33.341 21 53.464 34
    1.393 8.5 34.271 21.5 54.11 34.5
    3.2092 9 35.184 22 54.748 35
    4.9506 9.5 36.082 22.5

    6.624 10 36.965 23

    8.2352 10.5 37.834 23.5

    9.7896 11 38.688 24

    11.291 11.5 39.529 24.5

    12.745 12 40.358 25

    14.153 12.5 41.173 25.5

    15.52 13 41.977 26

    16.847 13.5 42.769 26.5


     
    Temperature Unit: centigrade
    Remark: 1KPa≈0.01kg/cm2=0.001MPa,1kg/cm2 ≈98.0665KPa≈0.1MPa
  • Q Top 10 most frequently asked questions by wholesalers about refrigerant gas R32

    A
    1. Is R32 a "drop-in" replacement for R410A?
    No, it is not. R32 is not suitable as a direct replacement for R410A and must only be used in systems specifically designed for it. R410A systems are not designed for flammable refrigerants and would require extensive modifications and laboratory validation to meet safety standards for R32 use.
     
    2. What are the key environmental properties of R32 (GWP and ODP)?
    R32 has an Ozone Depletion Potential (ODP) of 0, meaning it does not harm the ozone layer. Its Global Warming Potential (GWP) is significantly lower than many older refrigerants, such as R410A (GWP of 675 vs. 2088).
     
    3. What is the future regulatory outlook for R32?
    The regulatory outlook is a major concern. Under the revised EU F-Gas Regulation (EU) 2024/573, starting January 1, 2027, new split heat pumps and air conditioners with a capacity of 12kW or less will be banned from using refrigerants with a GWP greater than 150. Since R32 has a GWP of 675, it will be phased out for this specific, major application category.
     
    4. What safety classification and handling requirements apply to R32?
    R32 is classified as an A2L refrigerant, meaning it has "lower flammability". This requires specific safety measures:
     
    Licensing: In some regions like Australia, a refrigerant handling licence is required to work on R32 systems, and a trading authorisation is needed to buy it.
     
    Storage & Transport: It is classified as a dangerous goods class 2.1 flammable gas for transport, requiring more stringent handling and storage safeguards than non-flammable gases.
     
    Safety: It must be kept away from open flames and ignition sources, as burning it can create toxic substances like hydrogen fluoride. Asphyxiation and freeze burns are also risks when handling it in liquid form.
     
    5. What special equipment is needed to handle R32?
    Standard equipment is often not compatible. You must use equipment rated for use with A2L flammable refrigerants, including:
     
    R32-calibrated gauge manifold sets.
     
    Electronic refrigerant detectors specifically rated for A2L refrigerants.
     
    Vacuum pumps and recovery equipment rated for A2L refrigerants.
     
    Dedicated recovery cylinders for R32.
     
    6. Can an existing R410A system be converted to use R32?
    No. As mentioned above, it is not a suitable "drop-in" replacement. Converting a system designed for R410A to R32 would require extensive and costly redesign and laboratory safety testing to ensure compliance with all relevant standards.
     
    7. What are the typical packaging and minimum order quantities (MOQ)?
    Information from wholesalers and manufacturers gives some indication:
     
    Cylinder Sizes: Common packages include non-refillable steel cylinders (e.g., 8.15lb/3.7kg, 9.5kg/21lb), refillable steel cylinders (e.g. 9KG, 680KG etc..), and ISO-TANKS.
     
    Minimum Order Quantities (MOQ): 20ft container can load 1150 cylinders, the less you buy, the higher cost it will be.
     
    8. What is the recommended lubricating oil for R32?
    R32 systems use POE (Polyolester) oil.
     
    9. What are R32's thermodynamic properties?
    Key physical properties include:
     
    Boiling Point: Approximately -51.7°C (-61.1°F)
     
    Melting Point: Approximately -136°C
     
    Critical Temperature: Approximately 78.1°C (172.6°F)
     
    10. Why might R32 be risky for wholesalers to stock long-term?
    The primary risk is regulatory obsolescence. As outlined in question 3, the impending EU ban on R32 in split systems under 12kW starting in 2027 represents a major market restriction. This creates a risk of holding stock that will become non-compliant and unsellable for a key application sector, making it a transitional refrigerant rather than a long-term solution.

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