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  • Q Introduction of Refrigerant Gas R404a

    A
    Basic Introduction of Refrigerant Gas R404a
     
    R404A is a mixture of HFC125, HFC-134a and HFC-143. The ratio is R404A = 44% R125 + 4% R134A + 52% 143A. It is a colorless gas at room temperature, and a colorless and transparent liquid under its own pressure. R-404A is suitable for new commercial refrigeration equipment, transportation refrigeration equipment or renewal equipment at medium and low temperatures. Closest to R-502, this refrigerant is suitable for all environments where R-502 can operate normally.

    Product name: R404A (R-404A)

    Product Category: HFC

    Chemical composition: pentafluoroethane/trifluoroethane/tetrafluoroethane mixture

    Refrigerant R404A, alias R404A, product names include SUVA HP62, SUVA 404A, Genetron 404A, etc. As R404A belongs to the HFC-type non-azeotropic environmentally friendly refrigerant (completely does not contain ozone-depleting CFC, HCFC), it is currently recognized and recommended by most countries in the world as the mainstream low-temperature environmentally friendly refrigerant. Re-added during installation and maintenance. It complies with the standards of the US environmental protection organization EPA, SNAP and UL, and complies with the A1 safety level category of the American Society of Heating, Refrigeration and Air-Conditioning Engineers (ASHRAE) (this is the highest level and harmless to humans).


    Physical Properties

    Physical Properties
    Molecular Formula CHF2CF3/CF3CH2F/CH3CF3   
    Molecular Weight 97.6
    Boiling Point  101.3KPa(° C) -46.60
    Freezing Point
    Density 30°C(kg/m3) 1017.2
    Critical Temperature (°C)  72.1
    Critical Pressure (MPa) 3.74
    ODP 0
    GWP  3800

    Quality Index

    Quality Index
    Purity  ≥99.90% 
    Water content  ≤0.001% 
    Acidity ≤0.00001% 
    Evaporation residue  ≤0.01% 
    Chloride content N/M
    Appearance  Colorless and clear 
    Odor  Odorless 

    Application of R404a Refrigerant

    As a widely used medium and low temperature refrigerant today, R404A is often used in cold storage, food freezing equipment, marine refrigeration equipment, industrial low temperature refrigeration, commercial low temperature refrigeration, transportation refrigeration equipment (refrigerated trucks, etc.), refrigerated condensing units, supermarket display cabinets Wait for refrigeration equipment.

    Refrigerant R404A is the most common industry standard refrigerant (usually low temperature refrigeration system) to replace Freon R22 and R502 in newly installed refrigeration equipment. R404A is the closest to the operation of R-502, and it is suitable for all R-502 that can operate normally. Environment, R404A is recognized and used by most refrigeration equipment manufacturers in the world. However, because R404A is different from R502 and R22 in physical and chemical properties, theoretical cycle performance, and compressor oil, the after-sales maintenance of refrigeration equipment initially installed as R502 and R22 refrigerants, if you need to add or replace refrigerants, still Only R502 and R22 can be added, usually R404A cannot be used to replace R502 and R22 directly (that is, exchange-type replacement is usually not possible).

  • Q R404a Refrigerant Temperature and Relative Pressure

    A
    R404a Refrigerant Temperature and Relative Pressure
    Temp. Pressure
    kpa
    Temp. Pressure
    kpa
    Temp. Pressure
    kpa
    Temp. Pressure
    kpa
    Temp. Pressure
    kpa
    -60 0.05 -31 0.2 -2 0.569 27 1.31 56 2.63
    -59 0.053 -30 0.208 -1 0.588 28 1.36 57 2.68
    -58 0.056 -29 0.217 0 0.608 29 1.39 58 2.74
    -57 0.059 -28 0.226 1 0.628 30 1.43 59 2.81
    -56 0.062 -27 0.235 2 0.645 31 1.46 60 2.86
    -55 0.066 -26 0.243 3 0.665 32 1.5 61 2.93
    -54 0.069 -25 0.253 4 0.687 33 1.53 62 2.98
    -53 0.072 -24 0.264 5 0.71 34 1.57 63 3.05
    -52 0.076 -23 0.275 6 0.73 35 1.61 64 3.13
    -51 0.08 -22 0.284 7 0.752 36 1.66 65 3.19
    -50 0.084 -21 0.296 8 0.777 37 1.69 66 3.26
    -49 0.089 -20 0.306 9 0.8 38 1.73 67 3.31
    -48 0.093 -19 0.318 10 0.823 39 1.78 68 3.4
    -47 0.098 -18 0.33 11 0.85 40 1.82 69 3.45
    -46 0.103 -17 0.343 12 0.872 41 1.87 70 3.54
    -45 0.108 -16 0.354 13 0.9 42 1.91 71 3.6
    -44 0.112 -15 0.368 14 0.923 43 1.96 72 3.69
    -43 0.118 -14 0.381 15 0.95 44 2.03 73 3.75
    -42 0.124 -13 0.394 16 0.978 45 2.06 74 3.81
    -41 0.129 -12 0.407 17 1.01 46 2.09 75 3.87
    -40 0.136 -11 0.424 18 1.04 47 2.15

    -39 0.141 -10 0.438 19 1.06 48 2.2

    -38 0.149 -9 0.453 20 1.09 49 2.25

    -37 0.155 -8 0.468 21 1.12 50 2.29


     
    Temperature Unit: centigrade
    Remark: 1KPa≈0.01kg/cm2=0.001MPa,1kg/cm2 ≈98.0665KPa≈0.1MPa
     
  • Q 10 Most Frequently Asked Questions by Wholesalers and Importers About Importing R404A Gas

    A
    1. Is it still legal to import R404A, and what are the current restrictions?
    Answer: R404A is facing significant regulatory restrictions globally, though it is not outright banned everywhere yet. The key is understanding the specific rules for your target market.
     
    United States: Effective January 1, 2025, the EPA prohibits the use of R404A in new self-contained refrigerated transport (road and marine) equipment . Similar bans are phased in for automatic commercial ice machines and refrigerated food processing equipment through 2028 .
     
    European Union: The EU F-Gas Regulation is implementing a strict phase-down. From 2025-2026, only 24% of the 2015 HFC quantity can be placed on the market, with this halving again from 2027 . A new quota allocation fee of €3.00 per tonne of CO₂ equivalent also applies from January 2026 .
     
    Australia: Import quotas are being reduced. Supply constraints are already observed in 2026, with further reductions scheduled. A prohibition on bulk imports of R404A is proposed from 2028 .
     
    Practical Implication: You need an import license and F-gas certificate (in the EU) and must secure quota allocations before shipping.
     
    2. What documentation is required for customs clearance when importing R404A?
    Answer: Importing R404A requires a comprehensive set of documents beyond the standard commercial invoice and bill of lading.

    The critical documents include:
    Material Safety Data Sheet (MSDS): Must be provided by the manufacturer and submitted to customs and port authorities.
    Dangerous Goods Declaration: Required because R404A is classified as a non-flammable, non-toxic gas (Class 2.2) under international transport regulations (IMDG for sea, IATA for air).
    UN Certification: Cylinders must bear valid UN pressure test certification marks.
    Import License/Permit: Many countries require a specific refrigerant import permit or F-gas license before the shipment arrives.
    Certificate of Origin: Essential for determining tariff rates and applying any free-trade agreement preferences.
    Bill of Lading/Air Waybill: Must correctly describe the goods with proper UN number (UN3337 for R404A in closed cryogenic vessels).
    Quota Allocation Proof: In markets like the EU, you must present evidence that you hold the necessary quota rights.
     
    Practical Implication: Missing any single document can result in customs holds, demurrage charges, or even rejection of the shipment at the port.
     
    3. What is the "phase-down" and how does it affect import quotas?
    Answer: The phase-down is a global agreement under the Kigali Amendment to the Montreal Protocol to gradually reduce the production and consumption of HFCs (like R404A) due to their high Global Warming Potential (GWP). 
     
    For importers, this means:
     
    Quota systems: Countries set annual import limits based on CO₂ equivalent (GWP). R404A has a GWP of ~3,922. This means importing 1kg of R404A consumes the same quota as importing ~3.9kg of a lower-GWP refrigerant like R134a (GWP ~1,400) or ~9.4kg of a very low-GWP alternative like R32 (GWP ~675) .
     
    Quota Allocation Fee (EU): From 2026, a levy is calculated on GWP. For R404A (GWP 3922), the fee is approximately €11.77 per kg .
     
    Practical Implication: You must apply for and secure quota allowances before importing, and the high GWP of R404A means you get less "quota capacity" per kilogram imported.
     
    4. What is the typical packaging and minimum order quantity (MOQ)?
    Answer: R404A is shipped in various packaging depending on the market and supplier, but wholesalers typically deal in bulk:
     
    Disposable Cylinders: 10.9 kg (24 lb) are common for export, especially from China. The MOQ for these is often high, e.g., 800-1,150 cylinders per 20-foot container .
     
    Refillable Cylinders: 45 kg and 8 kg cylinders are common for domestic supply in some markets .
     
    Bulk: Ton-tanks (e.g., 740 kg) and ISO containers (18 tons) are used for very large wholesale orders .
     
    MOQ: Because refrigerant gas is considered a dangerous good, it cannot typically be shipped by LCL (Less than Container Load). You must generally ship by full container load .
     
    5. What are the marking, labeling, and country of origin requirements?
    Answer: All imported refrigerant cylinders must be clearly and permanently marked with the country of origin (e.g., "Made in China") . For a product like R404A, if the final product (the gas mixture) is produced in China, the country of origin is China, even if the individual components are sourced elsewhere . Additionally, cylinders must carry standard safety and hazard labels (e.g., non-flammable, non-toxic A1 safety classification, GWP value) .
     
    Practical Implication: Ensure your supplier includes the correct country of origin on the cylinders and packaging before shipping to avoid customs delays.
     
    6. What are the technical specifications and purity requirements?
    Answer: R404A is a near-azeotropic blend of three HFCs:
     
    R-143a (52%)
    R-125 (44%)
    R-134a (4%) .
     
    Standard technical specifications typically require:
     
    Purity: ≥ 99.8% or 99.9% .
    Moisture: ≤ 0.001% .
    Acidity: ≤ 0.0001% .
    Non-condensable gas: ≤ 1.5% (v/v at 25°C) .
     
    These specifications ensure that the gas meets the standards for use in low and medium-temperature commercial refrigeration, including supermarket freezers, cold storage, ice machines, and vending machines .
     
    7. How is R404A typically charged, and what lubricant does it require?
    Answer: Due to its near-azeotropic nature (though it has a small temperature glide), R404A is best charged as a liquid to prevent fractionation, where the refrigerant blend separates into its components . It requires polyolester (POE) oil as the recommended lubricant for complete miscibility and proper oil return to the compressor . The lubricant is critical for large systems with long piping runs.
     
    Practical Implication: The lubricant requirement affects system retrofits and is not a direct concern for importers, but is a key question from end-users.
     
    8. Can I find recycled or reclaimed R404A, and is it subject to quotas?
    Answer: Yes, recycled (reclaimed) R404A is available and plays an important role in the market. For example, some EU-based suppliers stock recycled R404A, R134a, and other refrigerants . Crucially, recycled refrigerants are exempt from the EU's new quota allocation fee system . This makes reclaimed gas a more cost-effective and available option to help manage supply chain constraints and higher costs associated with virgin gas.
     
    9. What is the current supply outlook for R404A?
    Answer: The outlook is for tightening supply, increasing prices, and eventual scarcity.
     
    Australia: Import volumes were reduced in 2026, and supply constraints are already being observed . Major suppliers suggest R404A may become "increasingly scarce" within the next 6-12 months .
     
    EU: The quota system and phase-down are expected to push up prices significantly. For instance, in Europe, the new quota fee alone adds about €11.77 per kg to R404A (GWP 3922) .
     
    General: As countries aim to reduce HFC usage by 50% or more by 2028-2036, the availability of virgin R404A will continue to decline .
     
    Practical Implication: For wholesalers and importers, it is critical to secure supply early, consider investing in reclaimed gas, and plan for a transition to lower-GWP alternatives.
     
    10. What are the best alternative refrigerants for R404A?
    Answer: Many end-users are being forced to retrofit or replace systems. Common lower-GWP alternatives include R448A and R449A (GWP ~1,400). These are direct replacements for R404A in existing commercial refrigeration systems and allow importers to import about 2.5 times more quantity than R404A under the same CO₂ quota . However, it is worth noting that these alternatives may also face supply pressure over a 6-10 year horizon as demand increases . Natural refrigerants (like R290 and CO₂) are also emerging as long-term solutions .

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